Harmalkar, D.S.; Santosh, G.; Shetgaonkar, S.B.; Sankaralingam, M.; Dhuri, S.N.
(New Journal of Chemistry. 43(33); 2019; 12900-12906.)
A water-soluble manganese(V)-oxo species 1 was generated in the reaction of [Mn(III)(TPPS)Cl] 2 (TPPS = 5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine) and iodosylbenzene (PhIO) in 2:1 aqueous buffer (pH = 10.4): ...