| dc.contributor.author | Rane, K.S. | |
| dc.contributor.author | Verenkar, V.M.S. | |
| dc.contributor.author | Sawant, P.Y. | |
| dc.date.accessioned | 2015-06-03T07:29:22Z | |
| dc.date.available | 2015-06-03T07:29:22Z | |
| dc.date.issued | 2001 | |
| dc.identifier.citation | Bulletin of Materials Science. 24(3); 2001; 331-338. | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1007/BF02704931 | |
| dc.identifier.uri | http://irgu.unigoa.ac.in/drs/handle/unigoa/1248 | |
| dc.description.abstract | Iron oxyhydroxides and hydroxides were synthesized from chemically beneficiated high SiO2/Al2O3 low-grade iron ore (57(.)49 percent Fe2O3) rejects and heated to get iron oxides of 96-99(.)73 percent purity. The infrared band positions, isothermal weight loss and thermogravimetric and chemical analysis established the chemical formulas of iron-oxyhydroxides as gamma -FeOOH .0 .3H(2)O; alpha -FeOOH .0 .2H(2)O and amorphous FeOOH. The thermal products of all these were alpha -Fe2O3 excepting that of gamma -FeOOH .0 .3H(2)O which gave mainly gamma Fe2O3 and some admixture of alpha -Fe2O3. The hydrazinated iron hydroxides and oxyhydroxides, on the other hand, decomposed autocatalytically to mainly gamma -Fe2O3.Hydrazine method modifies the thermal decomposition path of the hydroxides, The saturation magnetization, J(s), values were found to be in the range 60-71 emu g(-1) which are close to the reported values for gamma -Fe2O3. Mechanism of the gamma -Fe2O3 formation by hydrazine method is discussed. | en_US |
| dc.publisher | Indian Academy of Sciences | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Ferrite grade iron oxides from ore rejects | en_US |
| dc.type | Journal article | en_US |
| dc.identifier.impf | y |