Synthesis, TG, DSC and infrared spectral study of NiMn2(C4H4O4)(3)center dot 6N(2)H(4)

Porob, R.A.; Khan, S.Z.; Mojumdar, S.C.; Verenkar, V.M.S.

dc.contributor.author	Porob, R.A.
dc.contributor.author	Khan, S.Z.
dc.contributor.author	Mojumdar, S.C.
dc.contributor.author	Verenkar, V.M.S.
dc.date.accessioned	2015-06-03T09:00:04Z
dc.date.available	2015-06-03T09:00:04Z
dc.date.issued	2006
dc.identifier.citation	Journal of Thermal Analysis and Calorimetry. 86(3); 2006; 605-608.	en_US
dc.identifier.uri	http://dx.doi.org/10.1007/s10973-006-7715-y
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/1850
dc.description.abstract	Nickel manganese succinato-hydrazinate (NiMn2(C4H4O4)(3)center dot 6N(2)H(4)), has been synthesized for the first time by a novel precursor technique and characterized by IR, AAS and XRD. Thermal decomposition of the compound was studied from room temperature (rT) to 800 degrees C by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis besides isothermal mass loss studies. The compound was found to decompose autocatalytically, once ignited. TG-DSC shows two steps decomposition i.e.dehydrazination followed by decarboxylation. The infrared spectral studies show the N-N stretching frequency at 972 cm(-1) suggesting a bidentate bridging structure of hydrazine molecule in (NiMn2(C4H4O4)(3)center dot 6N(2)H(4)).	en_US
dc.publisher	Springer Verlag (Germany); Akademiai Kiado	en_US
dc.subject	Chemistry	en_US
dc.title	Synthesis, TG, DSC and infrared spectral study of NiMn2(C4H4O4)(3)center dot 6N(2)H(4)	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y