Bis[(+/-)-trans-2-aminocyclohexylammonium] tetrathiomolybdate(VI) and trans-cyclohexane-1,4-diammonium tetrathiomolybdate(VI)

Srinivasan, B.R.; Naether, C.; Bensch, W.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Naether, C.
dc.contributor.author	Bensch, W.
dc.date.accessioned	2015-06-03T09:00:04Z
dc.date.available	2015-06-03T09:00:04Z
dc.date.issued	2006
dc.identifier.citation	Acta Crystallographica Section C-Crystal Structure Communications. 62; 2006; M98-M101.	en_US
dc.identifier.uri	http://dx.doi.org/10.1107/S0108270106001685
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/1855
dc.description.abstract	The structures of the title complexes, (C6H15N2)2[MoS4], (I), and (C6H16N2)[MoS4], (II), can be described as consisting of discrete tetra-hedral [MoS4]2- dianions that are linked to the organic ammonium cations via weak hydrogen-bonding inter-actions. The asymmetric unit of (I) consists of a single (plus or minus)-trans-2-amino-cyclo-hexyl-ammonium cation in a general position and an [MoS4]2- anion located on a twofold axis, while in (II), two crystallographically independent trans-cyclo-hexane-1,4-diammonium cations located on centres of inversion and one [MoS4]2- anion in a general position are found. The differing dispositions of the amine functionalities in the organic cations in the title complexes lead to different crystal packing arrangements in (I) and (II).	en_US
dc.publisher	International Union of Crystallography	en_US
dc.subject	Chemistry	en_US
dc.title	Bis[(+/-)-trans-2-aminocyclohexylammonium] tetrathiomolybdate(VI) and trans-cyclohexane-1,4-diammonium tetrathiomolybdate(VI)	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y