Bis[benzyl(methyl)ammonium] tetrasulfidotungstate(VI)

Srinivasan, B.R.; Girkar, S.V.; Raghavaiah, P.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Girkar, S.V.
dc.contributor.author	Raghavaiah, P.
dc.date.accessioned	2015-06-03T09:34:35Z
dc.date.available	2015-06-03T09:34:35Z
dc.date.issued	2007
dc.identifier.citation	Acta Crystallographica Section E-Structure Reports Online. 63; 2007; M3100-M3101.	en_US
dc.identifier.uri	http://dx.doi.org/10.1107/S1600536807058746
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/1985
dc.description.abstract	The title compound, (C8H12N)(2)[WS4], was synthesized by the aqueous reaction of ammonium tetrasulfidotungstate(VI) with benzyl( methyl) amine in a 1:2 molar ratio.The compound is isotypic with the corresponding Mo analogue, (C8H12N)(2)[MoS4], and its structure consists of a slightly distorted tetrahedral [WS4](2-) dianion and two crystallographically independent benzyl( methyl) ammonium cations, with all atoms located in general positions.The cations and anion are linked by weak N-H...S and C-H...S interactions, the strength and number of which can explain the observed W-S bond distances.	en_US
dc.publisher	International Union of Crystallography	en_US
dc.subject	Chemistry	en_US
dc.title	Bis[benzyl(methyl)ammonium] tetrasulfidotungstate(VI)	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y