Preparation and characterization of Co0.5Zn0.5Fe2(C4H2O4)(3).6N(2)H(4)

Gonsalves, L.R.; Verenkar, V.M.S.; Mojumdar, S.C.

dc.contributor.author	Gonsalves, L.R.
dc.contributor.author	Verenkar, V.M.S.
dc.contributor.author	Mojumdar, S.C.
dc.date.accessioned	2015-06-03T10:10:07Z
dc.date.available	2015-06-03T10:10:07Z
dc.date.issued	2009
dc.identifier.citation	Journal of Thermal Analysis and Calorimetry. 96(1); 2009; 53-57.	en_US
dc.identifier.uri	http://dx.doi.org/10.1007/s10973-008-9837-x
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2257
dc.description.abstract	A good precursor is foremost in the preparation of nanosized metal or mixed metal oxides. In the present study a novel precursor, cobalt zinc fumarato-hydrazinate Co0.5Zn0.5Fe2(C4H2O4)(3).6N(2)H(4) has been prepared which decompose at a much lower temperature to give nanosized mixed-metal oxides. X-ray investigations, confirms the formation of single spinel phase. The FTIR spectra show N-N stretching vibration at 965 cm(-1) which confirms the bidentate bridging hydrazine. The thermal decomposition of the precursor has been studied by isothermal, thermogravimetric and differential scanning calorimetric analysis. The precursor shows two-step dehydrazination followed by decarboxylation to form Co0.5Zn0.5Fe2O4, the chemical analysis of the sample is corroborative of this.	en_US
dc.publisher	Springer Verlag (Germany); Akademiai Kiado	en_US
dc.subject	Chemistry	en_US
dc.title	Preparation and characterization of Co0.5Zn0.5Fe2(C4H2O4)(3).6N(2)H(4)	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y