Synthesis and structural characterization of bis(n-propylammonium) tetrasulfidometalates

Srinivasan, B.R.; Naik, A.R.; Naether, C.; Bensch, W.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Naik, A.R.
dc.contributor.author	Naether, C.
dc.contributor.author	Bensch, W.
dc.date.accessioned	2015-06-03T10:12:32Z
dc.date.available	2015-06-03T10:12:32Z
dc.date.issued	2009
dc.identifier.citation	Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 48(6); 2009; 769-774.	en_US
dc.identifier.uri	http://nopr.niscair.res.in/handle/123456789/4685
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2276
dc.description.abstract	The reaction of (NH(4))(2)[MS(4)] (M = W, Mo) with n-propylamine (CH(3)-CH(2)-CH(2)-NH(2)) results in the formation of bis(n-propylammonium) tetrasulfidometalates (CH(3)-CH(2)-CH(2)-NH(3))(2)[MS(4)] (M = W (1): Mo (2)). Both compounds have been characterized by elemental analysis, IR, Raman and UV-vis spectra and crystal structures. Compounds, (1) and (2) are isostructural and crystallize in the centrosymmetric orthorhombic space group, Pnma. The structure consists of discrete slightly distorted tetrahedral tetrasulfidometalate [MS(4)](2-) anions of in symmetry, separated by two crystallographically independent n-propylannnonium cations located on mirror planes. The carbon atoms of the organic cations are disodered. A comparative Study of twelve tetrasulfidometalates crystallizing in the orthorhombic space group Pnma is presented.	en_US
dc.publisher	NISCAIR	en_US
dc.subject	Chemistry	en_US
dc.title	Synthesis and structural characterization of bis(n-propylammonium) tetrasulfidometalates	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y