First alkaline earth 2-carbarnoyl-4-nitrobenzoate: Synthesis and supramolecular structure

Srinivasan, B.R.; Shetgaonkar, S.Y.; Raghavaiah, P.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Shetgaonkar, S.Y.
dc.contributor.author	Raghavaiah, P.
dc.date.accessioned	2015-06-03T10:12:56Z
dc.date.available	2015-06-03T10:12:56Z
dc.date.issued	2009
dc.identifier.citation	Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 48(12); 2009; 1662-1666.	en_US
dc.identifier.uri	http://nopr.niscair.res.in/handle/123456789/6755?mode=simple
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2282
dc.description.abstract	2-Carbamoyl-4-nitrobenzoic acid (2-ca-4nbaH) -has been prepared by alkaline hydrolysis of 4-nitrophthalimide. Aqueous reaction of MgCO(3) with 2-ca-4nbaH results in the formation of [Mg(H(2)O)(6)](2-ca-4nba)(2), which crystallizes in the centrosymmetric monoclinic space group P2(l)/c with Mg(II) situated on an inversion center. The crystal structure consists of a distorted octahedral hexaaquamagnesium(II) cation and a free uncoordinated 2-ca-4nba anion. The cation and anion are involved in three varieties of H-bonding, interactions, resulting in a supramolecular bilayer of 2-ca74nba anions sandwiched between layers of [Mg-(H(2)O)(6)](2+) cations.	en_US
dc.publisher	NISCAIR	en_US
dc.subject	Chemistry	en_US
dc.title	First alkaline earth 2-carbarnoyl-4-nitrobenzoate: Synthesis and supramolecular structure	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y