Synthesis and characterization of bis(alkylammonium) tetrasulfidometalates

Srinivasan, B.R.; Girkar, S.V.; Naether, C.; Bensch, W.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Girkar, S.V.
dc.contributor.author	Naether, C.
dc.contributor.author	Bensch, W.
dc.date.accessioned	2015-06-04T02:44:45Z
dc.date.available	2015-06-04T02:44:45Z
dc.date.issued	2010
dc.identifier.citation	Journal of Coordination Chemistry. 63(6); 2010; 931-942.	en_US
dc.identifier.uri	http://dx.doi.org/10.1080/00958971003674425
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2417
dc.description.abstract	The synthesis and characterization of the bis(alkylammonium) tetrasulfidometalates, (EtNH(3))(2)[MS(4)] (M = W 1, Mo 2), [BuNH(3)](2)[MS(4)] (M = W 3; Mo 4) and (Et-enH(2))[WS(4)] 1-en (Et-en = N-ethylethane-1,2-diamine), are reported. Compound 1 crystallizes in the centrosymmetric orthorhombic space group Pnma and its structure consists of discrete slightly distorted tetrahedral [WS(4)](2-) of m symmetry, separated by two crystallographically independent (EtNH(3))(+) ions located on mirror planes. The carbons of one ethylammonium are disordered. Compound 1-en crystallizes in the centrosymmetric orthorhombic space group Pbca with all atoms situated in general positions. Its structure consists of discrete (Et-enH(2))(2+) and a slightly distorted tetrahedral [WS(4)](2-) with the cations and anions linked by several weak hydrogen bonds.	en_US
dc.publisher	Taylor and Francis	en_US
dc.subject	Chemistry	en_US
dc.title	Synthesis and characterization of bis(alkylammonium) tetrasulfidometalates	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y