Synthesis and structural characterization of 1-methylpiperazinediium tetrasulfidotungstate monohydrate

Srinivasan, B.R.; Naik, A.R.; Naether, C.; Bensch, W.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Naik, A.R.
dc.contributor.author	Naether, C.
dc.contributor.author	Bensch, W.
dc.date.accessioned	2015-06-04T02:44:45Z
dc.date.available	2015-06-04T02:44:45Z
dc.date.issued	2010
dc.identifier.citation	Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 49(4); 2010; 437-441.	en_US
dc.identifier.uri	http://nopr.niscair.res.in/handle/123456789/7828
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2419
dc.description.abstract	The reaction of (NH(4))(2)[WS(4)] with 1-methylpiperazine results in the formation of 1-methylpiperazinediium tetrasulfidotungstate monohydrate, in good yield. (Me-pipH(2))[WS(4)].H(2)O has been characterized by elemental analysis, IR, Raman and UV-vis spectra and its crystal structure. The title compound crystallizes in the centrosymmetric monoclinic space group P2(1)/c and its structure consists of a discrete, slightly distorted tetrahedral tetrasulfidotungstate anion, 1-methylpiperazinediium cation and lattice water, which are linked by five varieties of H-bonding interactions namely N-H...O, N-H...S, O-H...S, C-H...O and C-H...S. The lattice water links pairs of organic cations with pairs of [WS(4)](2-) anions via N-H...O, O-H...S, and C-H...O bonds, while the cations and anions are linked via N-H...S, and C-H...S bonds.	en_US
dc.publisher	NISCAIR	en_US
dc.subject	Chemistry	en_US
dc.title	Synthesis and structural characterization of 1-methylpiperazinediium tetrasulfidotungstate monohydrate	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y