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Structural, vibrational and thermal studies of a new nonlinear optical material: l-asparagine-l-tartaric acid

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dc.contributor.author Moovendaran, K.
dc.contributor.author Srinivasan, B.R.
dc.contributor.author Sundar, J.K.
dc.contributor.author Dhas, S.A.
dc.contributor.author Martin, B.
dc.contributor.author Natarajan, S.
dc.date.accessioned 2015-06-04T03:22:14Z
dc.date.available 2015-06-04T03:22:14Z
dc.date.issued 2012
dc.identifier.citation Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. 92; 2012; 388-391. en_US
dc.identifier.uri http://dx.doi.org/10.1016/j.saa.2012.02.089
dc.identifier.uri http://irgu.unigoa.ac.in/drs/handle/unigoa/2719
dc.description.abstract Crystals of a new nonlinear optical (NLO) material, viz., L-asparagine-L-tartaric acid (LALT)(1) were grown by slow evaporation of an aqueous solution containing equimolar concentrations of L-asparagine and t-tartaric acid. The structure of the title compound which crystallizes in the non-centrosymmetric monoclinic space group P2(1) consists of a molecule of L-asparagine and a molecule of free L-tartaric acid both of which are interlinked by three varieties of H-bonding interactions namely O-H...O, N-H...O and C-H...O. The UV-Vis-NIR spectrum of 1 reveals its transparent nature while the vibrational spectra confirm the presence of the functional groups in 1. The thermal stability and second harmonic generation (SHG) conversion efficiency of 1 were investigated. en_US
dc.publisher Elsevier en_US
dc.subject Chemistry en_US
dc.title Structural, vibrational and thermal studies of a new nonlinear optical material: l-asparagine-l-tartaric acid en_US
dc.type Journal article en_US
dc.identifier.impf y


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