A new calcium(II) coordination polymer based on a mu(2)-bridging tridentate 4-nitrobenzoate

Srinivasan, B.R.; Shetgaonkar, S.Y.; Saxena, M.; Naether, C.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Shetgaonkar, S.Y.
dc.contributor.author	Saxena, M.
dc.contributor.author	Naether, C.
dc.date.accessioned	2015-06-04T03:22:15Z
dc.date.available	2015-06-04T03:22:15Z
dc.date.issued	2012
dc.identifier.citation	Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 51(3); 2012; 435-443.	en_US
dc.identifier.uri	http://nopr.niscair.res.in/handle/123456789/13651
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/2729
dc.description.abstract	Reaction of a heptacoordinated Ca(II) compound [Ca(H2O)(4)(4-nba)(2)] (4-nba = 4-nitrobenzoate) with 3,5-dimethylpyrazole (dmp) leads to the formation of an eight coordinated Ca(II) compound, [[Ca(H2O)(2)(4-nba)(2)].2dmp](n), containing two coordinated water molecules, two unique 4-nba ligands and two free dmp molecules in the lattice. The mu(2)-bridging tridentate binding mode of the unique 4-nba ligands results in the formation of a one-dimensional (1-D) coordination polymer. The title compound exhibits enhanced fluorescence emission. An analysis of the six different bridging binding modes of the 4-nba ligand in twenty two different structurally characterized 4-nitrobenzoate compounds is described.	en_US
dc.publisher	NISCAIR	en_US
dc.subject	Chemistry	en_US
dc.title	A new calcium(II) coordination polymer based on a mu(2)-bridging tridentate 4-nitrobenzoate	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y