Coupling between suboxic condition in sediments of the western Bay of Bengal and southwest monsoon intensification: A geochemical study

Abstract

Reconstruction of paleo-redox conditions in a radiocarbon (14C) dated sediment core (SK-218/1), covering the past 45 ka (thousand calendar years), collected from the western Bay of Bengal (Lat: 14 degrees 02'N; Long: 82 degrees 00'E) at a water depth of 3307 m, has been made based on redox-sensitive element geochemistry. The high U/Th ratio, Mo enrichment, Mo/U enrichment factor ratio, Ce/Ce less than 1 and lower Mn/Al and Fe/Al ratios, compared to upper continental crust are all indicative of prevalence of suboxic condition in the benthic environment from 15.2 ka to 4.5 ka, peaking around 9.5 ka. The suboxic condition around 9.5 ka corresponds to the previously recorded southwest (SW) monsoon intensification in response to the increase in northern hemisphere summer insulation. However, productivity proxies - organic carbon and nitrogen contents - do not indicate marked increase in productivity at this time. It is proposed that as a result of large increase in lithogenic material supplied from land due to SW monsoon intensification, which is evident by the very high concentration of Al, Zr and Hf, the flux of fresh labile organic matter and these might have formed dense mineral matter - biogenic aggregates which sinks rapidly to the seafloor, and the degradation of labile organic matter might have led to the development of suboxic condition in the benthic environment. There exists a strong positive correlation (r = 0.98) between Mo and Zr during 15.2 ka to 4.5 ka suggesting a coupling between suboxic condition and lithogenic flux supply by the intensified SW monsoon. Our results suggest that temporal variability of the ballasting effect of the terrestrially-derived material could play a key role in benthic biogeochemistry and ecology of the Bay of Bengal.