Piperazinediium bis(mu2-phthalato)zincate(II) monohydrate: A new ladder coordination polymer with a unique supramolecular architecture

Jyai, R.N.; Srinivasan, B.R.

dc.contributor.author	Jyai, R.N.
dc.contributor.author	Srinivasan, B.R.
dc.date.accessioned	2015-11-19T02:21:08Z
dc.date.available	2015-11-19T02:21:08Z
dc.date.issued	2015
dc.identifier.citation	Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 54(); 2015; 1402-1408.	en_US
dc.identifier.uri	http://nopr.niscair.res.in/handle/123456789/30341
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/4229
dc.description.abstract	The mu2-bridging bidentate coordination modes of the crystallographically unique phthalate ligands in piperazinediium bis(mu2-phthalato)zincate(II) monohydrate (1) result in Zn...Zn separations of 5.839(5) and 8.142(3) Angstrom respectively leading to a one-dimensional Zn(II) ladder. The organic cation, ladder complex anion and lattice water in (pipH2)[Zn(pt)2].H2O (1) (pipH2= piperazinediium, pt = phthalate) assemble into a unique supramolecular network, resulting in the following H-bonded sequence, vis., water...cation...water...ladder...water in the crystallographic ac plane.	en_US
dc.publisher	NISCAIR	en_US
dc.subject	Chemistry	en_US
dc.title	Piperazinediium bis(mu2-phthalato)zincate(II) monohydrate: A new ladder coordination polymer with a unique supramolecular architecture	en_US
dc.type	Journal article	en_US
dc.identifier.impf	Y