dc.contributor.author |
Ganorkar, S. |
|
dc.contributor.author |
Priolkar, K.R. |
|
dc.contributor.author |
Sarode, P.R. |
|
dc.contributor.author |
Emura, S. |
|
dc.date.accessioned |
2016-05-16T07:09:27Z |
|
dc.date.available |
2016-05-16T07:09:27Z |
|
dc.date.issued |
2016 |
|
dc.identifier.citation |
International Conference on Condensed Matter and Applied Physics (ICC 2015). Bikaner, India. 30-31 Oct 2015.. AIP Conf. Proc. 1728; 2016; vp. |
en_US |
dc.identifier.uri |
http://dx.doi.org/10.1063/1.4946100 |
|
dc.identifier.uri |
http://irgu.unigoa.ac.in/drs/handle/unigoa/4350 |
|
dc.description.abstract |
The structural and magnetic properties of layered perovskites of the type RBaCo(2)O(5+delta) with delta less than or equal to 0.5 (R=Pr, Nd, Sm, Gd and Y) have been investigated. The samples were prepared by the sol-gel method and characterized by X-ray diffraction, magnetization and X-ray absorption near edge structure (XANES) spectroscopy. It is found that the magnetic properties depend on the size of the rare-earth ion. The critical size of the rare-earth ion introduces structural distortion which affects the Co-O hybridization in these layered perovskites. The detailed analysis of experimental and calculated XANES spectra throws some light on spin states of Co ions in these perovskites. |
en_US |
dc.publisher |
AIP |
en_US |
dc.subject |
Physics |
en_US |
dc.title |
X-ray spectroscopic and magnetic studies of RBaCo(2)O(5.5), R = Pr, Nd, Sm, Gd and Y |
en_US |
dc.type |
Conference article |
en_US |