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X-ray spectroscopic and magnetic studies of RBaCo(2)O(5.5), R = Pr, Nd, Sm, Gd and Y

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dc.contributor.author Ganorkar, S.
dc.contributor.author Priolkar, K.R.
dc.contributor.author Sarode, P.R.
dc.contributor.author Emura, S.
dc.date.accessioned 2016-05-16T07:09:27Z
dc.date.available 2016-05-16T07:09:27Z
dc.date.issued 2016
dc.identifier.citation International Conference on Condensed Matter and Applied Physics (ICC 2015). Bikaner, India. 30-31 Oct 2015.. AIP Conf. Proc. 1728; 2016; vp. en_US
dc.identifier.uri http://dx.doi.org/10.1063/1.4946100
dc.identifier.uri http://irgu.unigoa.ac.in/drs/handle/unigoa/4350
dc.description.abstract The structural and magnetic properties of layered perovskites of the type RBaCo(2)O(5+delta) with delta less than or equal to 0.5 (R=Pr, Nd, Sm, Gd and Y) have been investigated. The samples were prepared by the sol-gel method and characterized by X-ray diffraction, magnetization and X-ray absorption near edge structure (XANES) spectroscopy. It is found that the magnetic properties depend on the size of the rare-earth ion. The critical size of the rare-earth ion introduces structural distortion which affects the Co-O hybridization in these layered perovskites. The detailed analysis of experimental and calculated XANES spectra throws some light on spin states of Co ions in these perovskites. en_US
dc.publisher AIP en_US
dc.subject Physics en_US
dc.title X-ray spectroscopic and magnetic studies of RBaCo(2)O(5.5), R = Pr, Nd, Sm, Gd and Y en_US
dc.type Conference article en_US


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