Catalytic activity and mechanistic approach of NO reduction by CO over M(0.05)Co(2.95)O(4) (M = Rh, Pd and Ru) spinel system

Salker, A.V.; FalDesai, M.S.

dc.contributor.author	Salker, A.V.
dc.contributor.author	FalDesai, M.S.
dc.date.accessioned	2016-08-04T04:43:12Z
dc.date.available	2016-08-04T04:43:12Z
dc.date.issued	2016
dc.identifier.citation	Applied Surface Science. 389(); 2016; 344-353.	en_US
dc.identifier.uri	http://dx.doi.org/10.1016/j.apsusc.2016.07.121
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/4432
dc.description.abstract	Pd, Rh and Ru doped cobalt oxide spinels have been prepared by citric acid assisted sol-gel method to yield nano-catalysts. Compositions have been characterized by XRD, FTIR, TG/DTA, BET, SEM, TEM, TPD and XPS techniques. Simultaneous catalytic detoxification of nitric oxide and carbon monoxide is investigated over the doped and pristine catalysts. Metal doping is found to enhance the activity of the catalysts due to their better adsorption capacity. Moisture and oxygen tolerance is investigated for Rh and Pd substituted catalysts. A probable reaction mechanism on the catalyst surface has been proposed.	en_US
dc.publisher	Elsevier	en_US
dc.subject	Chemistry	en_US
dc.title	Catalytic activity and mechanistic approach of NO reduction by CO over M(0.05)Co(2.95)O(4) (M = Rh, Pd and Ru) spinel system	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y