dc.contributor.author |
Shetgaonkar, A.D. |
|
dc.contributor.author |
Nadkarni, V.S. |
|
dc.date.accessioned |
2019-11-18T05:07:21Z |
|
dc.date.available |
2019-11-18T05:07:21Z |
|
dc.date.issued |
2019 |
|
dc.identifier.citation |
ChemistrySelect. 4(42); 2019; 12210-12215. |
en_US |
dc.identifier.uri |
https://doi.org/10.1002/slct.201903243 |
|
dc.identifier.uri |
http://irgu.unigoa.ac.in/drs/handle/unigoa/5892 |
|
dc.description.abstract |
A series of dumbbell-shaped urethane connecting polyoleifinic dendrimers, are synthesized from commercial AB sub(2) monomer through the concept of post-generative synthetic induction of novel 1->4-C branching motif in divergent and convergent growth methodology using carbamoyl chloride reactivity. A synthetic protocol is conducted through the iterative process of O-carbamoyl-allylation of hydroxyls followed by Upjohn dihydroxylation of the allylic double bonds, leading to protection/deprotection free divergent pathway. In parallel, convergent growth route gains dendrimers in relatively good yields. Also, the process of O-carbonyloxy-allylation of [G-1] polyol affords urethane-carbonate framework providing access to 1->2-C branching further. Incorporation of current branching motif results in dendritic scaffold with dense periphery at lower generations itself. Free radical cast polymerization of [G-0.5] dendrimer with allyl diglycol carbonate (ADC) produces thermoset polymer films, showing good sensitivity and ability to permanently record nuclear tracks. |
en_US |
dc.publisher |
Wiley |
en_US |
dc.subject |
Chemistry |
en_US |
dc.title |
Synthetically induced 1->4-C branching motif - An access towards dense urethane connecting dendritic scaffolds and application in nuclear track detection |
en_US |
dc.type |
Journal article |
en_US |
dc.identifier.impf |
y |
|