IR @ Goa University

Aggregation-induced emission characteristics and solvent triggered hierarchical self-assembled chiral superstructures of naphthalenediimide amphiphiles

Show simple item record

dc.contributor.author Shejul, D.A.
dc.contributor.author Wagalgave, S.M.
dc.contributor.author Jadhav, R.W.
dc.contributor.author Kobaisi, M.A.
dc.contributor.author La, D.D.
dc.contributor.author Jones, L.A.
dc.contributor.author Bhosale, R.S.
dc.contributor.author Bhosale, Sidhanath V.
dc.contributor.author Bhosale, S.V.
dc.date.accessioned 2020-01-06T08:47:06Z
dc.date.available 2020-01-06T08:47:06Z
dc.date.issued 2020
dc.identifier.citation New Journal of Chemistry. 44(4); 2020; 1615-1623. en_US
dc.identifier.uri http://doi.org/10.1039/C9NJ05137F
dc.identifier.uri http://irgu.unigoa.ac.in/drs/handle/unigoa/5932
dc.description.abstract Herein, we report the design and synthesis of two naphthalene diimide amphiphiles NDI-TA1 and NDI-TA2 bearing acylated and deacylated hydroxyl groups of tartaric acid, respectively. Furthermore, we investigated the influence of acylation and deacylation of hydroxyl groups of tartaric acid over UV-vis, aggregation induced emission (AIE), chirality and supramolecular self-assembly formation. Bottom-up supramolecular self-assembly formation approach of NDI-TA1 amphiphile exhibited biomimetic hairy caterpillar-like superstructures in THF/MCH solvent system 30:70 v/v whereas, long uniform helical ribbons were also yielded at higher volume percentage of MCH in THF (90:10 v/v). Circular dichroism (CD) spectroscopy study revealed a chiral aspect of the self-assembled supramolecular structures at wavelength corresponding to their absorptions. Interestingly, NDI-TA1 aggregates at higher amount of MCH in THF exhibited AIE property because of excimer formation. On the other hand, NDI-TA2 amphiphile displays total quenching of emission i.e. aggregation cause quenching (ACQ) effect. The SEM images of deacylated amphiphile NDI-TA2 produces belts and sheets-like supramolecular self-assembled microstructures. en_US
dc.publisher Royal Society of Chemistry en_US
dc.subject Chemistry en_US
dc.title Aggregation-induced emission characteristics and solvent triggered hierarchical self-assembled chiral superstructures of naphthalenediimide amphiphiles en_US
dc.type Journal article en_US
dc.identifier.impf y


Files in this item

This item appears in the following Collection(s)

Show simple item record

Search IR


Advanced Search

Browse

My Account