Diaquatetrakis(mu-3-methoxybenzoato-k sup(2)O sup(1):O sup(1)-dicopper(II)

Srinivasan, B.R.; Bhargao, P.H.; Sudhadevi, P.K.

dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Bhargao, P.H.
dc.contributor.author	Sudhadevi, P.K.
dc.date.accessioned	2020-04-27T06:52:19Z
dc.date.available	2020-04-27T06:52:19Z
dc.date.issued	2020
dc.identifier.citation	IUCrData. 5(4); 2020; CCDC reference: 1993956.	en_US
dc.identifier.uri	https://doi.org/10.1107/S2414314620004484
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/6031
dc.description.abstract	The asymmetric unit of the binuclear title compound, [Cu sub(2)(C sub(8)H sub(7)O sub(3)) sub(4)(H sub(2)O) sub(2)], comprises two halves of diaquatetrakis(μ-3-methoxybenzoato-k sup(2)O sup(1):O sup(1)-dicopper(II) units. The paddle-wheel structure of each complex is completed by application of inversion symmetry, with the inversion centre situated at the midpoint between two Cu sup(II) atoms in each dimer. The two CuII atoms of each centrosymmetric dimer are bridged by four 3-methoxybenzoate anions resulting in Cu...Cu separations of 2.5961 (11) and 2.6060 (12) Å, respectively. The square-pyramidal coordination sphere of each CuII atom is completed by an apical water molecule. Intermolecular O—H...O hydrogen bonds of weak nature link the complexes into layers parallel to (100). The three-dimensional network structure is accomplished by C—H...O hydrogen bonds interlinking adjacent layers.	en_US
dc.publisher	International Union of Crystallography	en_US
dc.subject	Chemistry	en_US
dc.title	Diaquatetrakis(mu-3-methoxybenzoato-k sup(2)O sup(1):O sup(1)-dicopper(II)	en_US
dc.type	Journal article	en_US