A Zinc(II) coordination polymer based on a chain of {Zn sub(2) O sub(7)} bitetrahedra bridged by 3-methoxybenzoates

Bhargao, P.H.; Hathwar, V.R.; Srinivasan, B.R.

dc.contributor.author	Bhargao, P.H.
dc.contributor.author	Hathwar, V.R.
dc.contributor.author	Srinivasan, B.R.
dc.date.accessioned	2020-08-25T06:42:18Z
dc.date.available	2020-08-25T06:42:18Z
dc.date.issued	2020
dc.identifier.citation	ChemistrySelect. 5(31); 2020; 9820-9824.	en_US
dc.identifier.uri	https://doi.org/10.1002/slct.202002457
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/6187
dc.description.abstract	The synthesis, crystal structure and properties of a zinc(II) coordination polymer viz. [Zn sub(2)(mu -OH)(mu sub(2-)eta sup(1):eta sup(1)-3-mba) sub(3)] 1 (3-mba=3-methoxybenzoate) based on 3-methoxybenzoic acid is described. The three crystallographically independent mu sub(2)- eta sup(1): eta sup(1) 3-mba ligands and the unique mu -hydoxide ligand link the two unique Zn(II) ions into an infinite chain of {Zn sub(2) O sub(7)} bitetrahedra with alternating Zn...Zn separations of 3.314 and 3.364 angstrom respectively. The carboxylate carbons of the symmetric bridging 3-mba ligands serve as links between the adjacent bitetrahedra in the coordination polymer. Pyrolysis of 1 results in the formation of highly agglomerated ZnO particles having spherical morphology. 1 exhibits blue fluorescence.	en_US
dc.publisher	Wiley	en_US
dc.subject	Chemistry	en_US
dc.subject	Physics	en_US
dc.title	A Zinc(II) coordination polymer based on a chain of {Zn sub(2) O sub(7)} bitetrahedra bridged by 3-methoxybenzoates	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y