dc.contributor.author |
Srinivasan, B.R. |
|
dc.contributor.author |
Kundaikar, S.A. |
|
dc.contributor.author |
Morajkar, S.M. |
|
dc.contributor.author |
Naether, C. |
|
dc.contributor.author |
Bensch, W. |
|
dc.date.accessioned |
2021-08-17T05:29:27Z |
|
dc.date.available |
2021-08-17T05:29:27Z |
|
dc.date.issued |
2021 |
|
dc.identifier.citation |
Journal of Coordination Chemistry. 74(13); 2021; 2239-2252. |
en_US |
dc.identifier.uri |
https://doi.org/10.1080/00958972.2021.1965996 |
|
dc.identifier.uri |
http://irgu.unigoa.ac.in/drs/handle/unigoa/6533 |
|
dc.description.abstract |
An attempted isolation of the elusive diammonium tetraoxidotungstate (NH sub(4)) sub(2)[WO sub(4)] as its imidazole (Im) adduct resulted in the serendipitous formation of hepta(ammonium) penta(1H-imidazol-3-ium) paratungstate B tetrahydrate having formula [NH sub(4)] sub(7)[ImH] sub(5)[W sub(12)O sub(42)].4H sub(2)O (1). The synthesis, vibrational spectra, crystal structure and thermal study of the mixed cationic paratungstate tetrahydrate 1 are reported. The structure of 1 consists of a centrosymmetric paratungstate [W sub(12)O sub(42)] sup(12-) anion devoid of internal hydrogen atoms, which is charge balanced by ammonium and 1H-imidazol-3-ium cations. One of the four unique NH sub(4)+ cations and one of the three crystallographically independent 1H-imidazol-3-ium cations are disordered around a center of inversion. The cations, [W sub(12)O sub(42)] sup(12-) anion and the unique lattice water molecules are joined with the aid of five varieties of hydrogen bonding interactions. A comparative study of twenty-three partaungstates is described. Thermal decomposition of 1 results in the formation of monoclinic tungsten trioxide WO sub(3). |
en_US |
dc.publisher |
Taylor & Francis |
en_US |
dc.subject |
Chemistry |
en_US |
dc.title |
Synthesis, crystal structure and properties of hepta(ammonium) penta(1H-imidazol-3-ium) paratungstate B tetrahydrate |
en_US |
dc.type |
Journal article |
en_US |
dc.identifier.impf |
y |
|