Structural, spectroscopic characterization and application of a Co(II) coordination polymer [Co(suc)(bpm)].2H sub(2)O

D'Souza, L.R.; Harmalkar, N.N.; Dhuri, S.N.

dc.contributor.author	D'Souza, L.R.
dc.contributor.author	Harmalkar, N.N.
dc.contributor.author	Dhuri, S.N.
dc.date.accessioned	2023-02-23T09:25:36Z
dc.date.available	2023-02-23T09:25:36Z
dc.date.issued	2022
dc.identifier.citation	ChemistrySelect. 7(46); 2022; ArticleID_e202203016.	en_US
dc.identifier.uri	https://doi.org/10.1002/slct.202203016
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/6975
dc.description.abstract	A Co(II) coordination polymer [Co(suc)(bpm)].2H sub(2)O (1) built from succinate (suc) and bipyrimidine (bpm) is synthesized hydrothermally and characterized by different methods. It crystallizes in a monoclinic space group P2 sub(1)/n with an intriguing 3D polymeric architecture. The weak antiferromagnetic (AF) exchange interactions were evinced by Curie Constant (C)=1.803 cm sup(3)mol sup(-1)K and a negative Weiss constant (Phi)=-30.163 K. Type VI adsorption isotherm behavior of 1 at 77 K revealed its non-porous property. Compound 1 was investigated and successfully utilized as an additive in lowering the decomposition temperature of ammonium nitrate (AN) based fuels as demonstrated from TG and DSC experiments performed in nitrogen atmosphere.	en_US
dc.publisher	Wiley	en_US
dc.subject	Chemistry	en_US
dc.title	Structural, spectroscopic characterization and application of a Co(II) coordination polymer [Co(suc)(bpm)].2H sub(2)O	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y