Browsing by Author "Nagarajan, K."

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Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N](2)[MoO2{S2C2(CN)(2)}(2)] in the model reductive half reaction of sulfite oxidase

Nagarajan, K.; Chaudhury, P.K.; Srinivasan, B.R.; Sarkar, S. (Chemical Communications. (18); 2001; 1786-1787.)

pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of ...
Reaction of model sulphite oxidase with dimethylsulphite

Chaudhury, P.K.; Nagarajan, K.; Srinivasan, B.R.; Sarkar, S. (Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 41; 2002; 139-140.)
Synthesis and x-ray structure characterization of ethylenediammonium tetrathiomolybdate

Srinivasan, B.R.; Vernekar, B.K.; Nagarajan, K. (Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 40(6); 2001; 563-567.)

The passage of hydrogen sulphide gas into an aqueous ammonium heptamolybdate solution in the presence of ethylenediamine leads to the formation of stable ethylenediammonium tetrathiomolybdate 1 in good yields. The title ...

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