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Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N](2)[MoO2{S2C2(CN)(2)}(2)] in the model reductive half reaction of sulfite oxidase

Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N](2)[MoO2{S2C2(CN)(2)}(2)] in the model reductive half reaction of sulfite oxidase

Nagarajan, K.; Chaudhury, P.K.; Srinivasan, B.R.; Sarkar, S.
Source : Chemical Communications. (18); 2001; 1786-1787.
URI: http://dx.doi.org/10.1039/b105341h
http://irgu.unigoa.ac.in/drs/handle/unigoa/1244
Date: 2001
Document Type: Journal article

Abstract:

pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.

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