Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N](2)[MoO2{S2C2(CN)(2)}(2)] in the model reductive half reaction of sulfite oxidase

Nagarajan, K.; Chaudhury, P.K.; Srinivasan, B.R.; Sarkar, S.

dc.contributor.author	Nagarajan, K.
dc.contributor.author	Chaudhury, P.K.
dc.contributor.author	Srinivasan, B.R.
dc.contributor.author	Sarkar, S.
dc.date.accessioned	2015-06-03T07:29:22Z
dc.date.available	2015-06-03T07:29:22Z
dc.date.issued	2001
dc.identifier.citation	Chemical Communications. (18); 2001; 1786-1787.	en_US
dc.identifier.uri	http://dx.doi.org/10.1039/b105341h
dc.identifier.uri	http://irgu.unigoa.ac.in/drs/handle/unigoa/1244
dc.description.abstract	pH dependent reactivity differences of dimethylsulfite towards the title complex 1 demonstrate the crucial need of oxo-anionic coordination of sulfite to the molybdenum centre of 1 in the model reductive half reaction of sulfite oxidase.	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Chemistry	en_US
dc.title	Oxoanionic or sulfur lone pair attack? The difference in reactivity of hydrogensulfite anion and neutral dimethylsulfite towards [Bu4N](2)[MoO2{S2C2(CN)(2)}(2)] in the model reductive half reaction of sulfite oxidase	en_US
dc.type	Journal article	en_US
dc.identifier.impf	y