Synthesis and structure of tris (acetylacetonato) aluminum(III)

Shirodker, M.; Borker, V.; Naether, C.; Bensch, W.; Rane, K.S.

Synthesis and structure of tris (acetylacetonato) aluminum(III)

Shirodker, M.; Borker, V.; Naether, C.; Bensch, W.; Rane, K.S.

Source : Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 49(12); 2010; 1607-1611.

URI: http://nopr.niscair.res.in/handle/123456789/10727
http://irgu.unigoa.ac.in/drs/handle/unigoa/2416

Date: 2010

Document Type: Journal article

Abstract:

Tris(acetylacetonato)aluminium(III), [Al(C2H7O2)(3)], a precursor in vapor deposition of aluminum oxide, has been prepared starting from industrial alum, Al-2(SO4)(3).16H(2)O and characterized by chemical, IR, thermal (TG-DSC) and single crystal X-ray diffraction analyses. The compound crystallizes in the monoclinic space group P2(1)/c and all atoms are located in general positions. The central metal is hexacoordinated to three bidentate acetyl acetonate ligands.

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