Synthesis and characterization of a mixed cationic tetrasulfidotungstate monohydrate

Srinivasan, B.R.; Mhalsikar, Rathan G.; Naether, C.; Bensch, W.

Synthesis and characterization of a mixed cationic tetrasulfidotungstate monohydrate

Srinivasan, B.R.; Mhalsikar, Rathan G.; Naether, C.; Bensch, W.

Source : Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical and Analytical Chemistry. 49(7); 2010; 891-895.

URI: http://nopr.niscair.res.in/handle/123456789/9922
http://irgu.unigoa.ac.in/drs/handle/unigoa/2418

Date: 2010

Document Type: Journal article

Abstract:

Synthesis and structural characterization of a mixed cationic tetrasulficlotungstate monohydrate (dabcoH)(3)(NMe(4))[WS(4)](2).H(2)O (dabco = 1,4-diazabicyclo[2.2.2]octane; NMe(4) = tetramethylammonium) is described. The compound crystallizes in the centrosymmetric monoclinic space group P2(1)/c and its structure consists of three crystallographically independent monoprotonated (dabcoH)(+) cations, a tetramethylammonium cation, two unique tetrasulfidotungstate anions, and a lattice water. The organic cations, [WS(4)](2-) anion and lattice water are linked by several weak H-bonding interactions.

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