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Total synthesis of bisabolane sesquiterpenoids, alpha-bisabol-l-one, curcumene, curcuphenol and elvirol: Utility of catalytic enamine reaction in cyclohexenone synthesis

Total synthesis of bisabolane sesquiterpenoids, alpha-bisabol-l-one, curcumene, curcuphenol and elvirol: Utility of catalytic enamine reaction in cyclohexenone synthesis

Hagiwara, H.; Okabe, T.; Ono, H.; Kamat, V.P.; Hoshi, T.; Toshio Suzuki, T.; Ando, M.
Source : Journal of Chemical Society, Perkin Transactions. 1; 2002; 895-900.
URI: http://irgu.unigoa.ac.in/drs/handle/unigoa/3589
Date: 2002
Document Type: Journal article

Abstract:

Total syntheses of alpha-bisabol-l-one, curcumene, curcuphenol and elvirol have been accomplished via 1,4-conjugate addition of intact aldehydes to vinyl ketones followed by an intramolecular aldol condensation.

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