Abstract:
The authors of the title paper (Mat. Lett. 272 (2020) 127899) report to have synthesized novel silver co-ordinated thiourea single crystals viz. TuAgN (1:1) (I) (Tu=thiourea; AgN=AgNO sub(3)) and TuAgN (4:1) (II) by mechanochemical stirring process. A critical analysis of the reported results reveals that both (I) and (II) are improperly characterized materials.