Abstract:
In this paper, we described the design, synthesis, and characterization of two novel naphthalene diimide (NDI) core-based targets modified with terminal fullerene (C sub(60)) yield - so called S4 and S5, in which NDI bearing 1 and 2 molecules of C sub(60), respectively. The absorption, electrochemical and thin-film transistor characteristics of the newly developed targets were investigated in detail. Both S4 and S5 displayed broad absorption in the 450-500 nm region, owing to the effect of conjugation due to fullerene functionalities. The electrochemical measurement suggested that the HOMO and the LUMO energy levels can be altered with the number of C sub(60) units. Both S4 and S5 were employed as organic semiconductor materials in n-channel transistors. The thin film transistor based on S4 exhibited superior electron mobility (Mu e) values ranging from 1.20x10 sup(-4) to 3.58x10 sup(-4) cm sup(2) V sup(-1) s sup(-1) with a current on-off ratio varying from 10 sup(2) to 10 sup(3) in comparison with the performance of S5 based transistor, which exhibited Mu e ranging from 8.33x10 sup(-5) to 2.03x10 sup(-4) cm sup(2) V sup(-1) s sup(-1) depending on channel lengths.
